Conjugated Polymer Nanoparticles Based on Anthracene and Tetraphenylethene for Nitroaromatics Detection in Aqueous Phase
نویسندگان
چکیده
The sensitive and selective detection of nitroaromatic explosives is great significance to national security human health. Herein, the novel linear polymer l-PAnTPE cross-linked PAnTPE nanoparticles based on anthracene tetraphenylethene groups were designed successfully synthesized via Suzuki-miniemulsion polymerization. particle sizes polymers are around 73 nm, making them well dispersible in water. exhibits porous structure, which beneficial for diffusion/adsorption analytes. fluorescence sensing towards nitroaromatics was performed aqueous phase, showed different quenching degree nitroaromatics. Among them, constant KSV values 2,4,6-trinitrophenol (TNP) reach 1.8 × 104 M−1 4.0 M−1, respectively, 1–2 orders magnitude higher than other explosives, thus demonstrating high sensitivity selectivity TNP phase. mechanism further discussed clarify this phenomenon by analyzing UV–Vis absorption, excitation, spectra, cyclic voltammograms decay measurements. In addition, paper strips tests exhibit that have potential application fast, low-cost on-site detection.
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ژورنال
عنوان ژورنال: Chemosensors
سال: 2022
ISSN: ['2227-9040']
DOI: https://doi.org/10.3390/chemosensors10090366