Conjugated Polymer Nanoparticles Based on Anthracene and Tetraphenylethene for Nitroaromatics Detection in Aqueous Phase

نویسندگان

چکیده

The sensitive and selective detection of nitroaromatic explosives is great significance to national security human health. Herein, the novel linear polymer l-PAnTPE cross-linked PAnTPE nanoparticles based on anthracene tetraphenylethene groups were designed successfully synthesized via Suzuki-miniemulsion polymerization. particle sizes polymers are around 73 nm, making them well dispersible in water. exhibits porous structure, which beneficial for diffusion/adsorption analytes. fluorescence sensing towards nitroaromatics was performed aqueous phase, showed different quenching degree nitroaromatics. Among them, constant KSV values 2,4,6-trinitrophenol (TNP) reach 1.8 × 104 M−1 4.0 M−1, respectively, 1–2 orders magnitude higher than other explosives, thus demonstrating high sensitivity selectivity TNP phase. mechanism further discussed clarify this phenomenon by analyzing UV–Vis absorption, excitation, spectra, cyclic voltammograms decay measurements. In addition, paper strips tests exhibit that have potential application fast, low-cost on-site detection.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Graphene based nanosensor for aqueous phase detection of nitroaromatics

A graphene-based nanosensor was fabricated to selectively detect nitrotriazolone (NTO) molecules with a molecularly imprinted film via simple electrical measurements. Molecularly imprinted polymer comprising chitosan was used as sensitive layer. Gold electrodes for electrical measurements were lithographically fabricated on Si/SiO2 substrate, followed by monolayer graphene transfer and polymeri...

متن کامل

Conjugated Polymer Nanoparticles for Bioimaging

During the last decade, conjugated polymers have emerged as an interesting class of fluorescence imaging probes since they generally show high fluorescence brightness, high photostability, fast emission rates, non-blinking behavior and low cytotoxicity. The main concern related to most conjugated polymers is their lack of hydrophilicity and thereby poor bio-availability. This can, however, be o...

متن کامل

Conjugated polymer nanoparticles.

Conjugated polymer nanoparticles are highly versatile nano-structured materials that can potentially find applications in various areas such as optoelectronics, photonics, bio-imaging, bio-sensing and nanomedicine. Their straightforward synthesis in desired sizes and properties, biocompatibility and non-toxicity make these materials highly attractive for the aforementioned applications. This fe...

متن کامل

Detection of TNT based on conjugated polymer encapsulated in mesoporous silica nanoparticles through FRET.

Amine-functionalized mesoporous silica nanoparticles containing poly(p-phenylenevinylene) provide a facile strategy to detect TNT through fluorescence resonance energy transfer (FRET). The observed linear fluorescence intensity change allows the quantitative detection of TNT with the detection limit of 6 × 10(-7) M.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Chemosensors

سال: 2022

ISSN: ['2227-9040']

DOI: https://doi.org/10.3390/chemosensors10090366